HRID319208

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID8028

Tetrahydrofuran

C4H8O

结构：O=S(=O)(c1ccccc1)N(F)S(=O)(=O)c1ccccc1

HCID588007

N-Fluorobenzenesulfonimide

C12H10FNO4S2

结构：CC(C)[Si](C(C)C)(C(C)C)n1ccc2c(Br)ccnc21

HCID11473655

未命名化合物

HCID178418306

未命名化合物

PRODUCTS

生成物

结构：CC(C)[Si](C(C)C)(C(C)C)n1ccc2c(F)ccnc21

HCID11266334

4-Fluoro-1-[tri(propan-2-yl)silyl]-1H-pyrrolo[2,3-b]pyridine

C16H25FN2Si

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-5b29b711696c49ed862432175b9eb387
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (8/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (8/10)

反应 SMILES

[Br:1][c:2]1[c:3]2[c:4]([n:5][cH:6][cH:7]1)[n:8]([Si:11]([CH:12]([CH3:13])[CH3:14])([CH:15]([CH3:16])[CH3:17])[CH:18]([CH3:19])[CH3:20])[cH:9][cH:10]2.[C:21]([Li:22])([CH3:23])([CH3:24])[CH3:25].[CH2:46]1[O:47][CH2:48][CH2:49][CH2:50]1.[F:26][N:27]([S:28]([c:29]1[cH:30][cH:31][cH:32][cH:33][cH:34]1)(=[O:35])=[O:36])[S:37]([c:38]1[cH:39][cH:40][cH:41][cH:42][cH:43]1)(=[O:44])=[O:45]>>[c:2]1([F:26])[c:3]2[c:4]([n:5][cH:6][cH:7]1)[n:8]([Si:11]([CH:12]([CH3:13])[CH3:14])([CH:15]([CH3:16])[CH3:17])[CH:18]([CH3:19])[CH3:20])[cH:9][cH:10]2