Acetate → HCID 178436249, compound

HRID 319321Notes

Reaction equation

HRID 319321 reaction equation
[C:124]([O-:125])(=[O:126])[CH3:127].[C:129]([O-:130])(=[O:131])[CH3:132].[C:1]([c:2]1[cH:3][c:4]2[c:5]([cH:6][cH:7]1)[c:8]([O:9][SiH:10]([CH3:11])[CH3:12])[c:13]([Bi:14]([c:15]1[cH:16][cH:17][c:18]3[c:19]([cH:20][cH:21][c:22]([C:23]([CH3:24])([CH3:25])[CH3:26])[cH:27]3)[c:28]1[O:29][SiH:30]([CH3:31])[CH3:32])[c:38]1[c:39]([O:52][SiH:53]([CH3:54])[CH3:55])[c:40]3[cH:41][cH:42][c:43]([C:48]([CH3:49])([CH3:50])[CH3:51])[cH:44][c:45]3[cH:46][cH:47]1)[cH:33][cH:34]2)([CH3:35])([CH3:36])[CH3:37].[C:56]([O:57][OH:58])(=[O:59])[CH3:60].[CH2:116]1[O:117][CH2:118][CH2:119][CH2:120]1.[CH2:121]([Cl:122])[Cl:123].[CH2:61]([CH3:62])[CH:63]1[C:64](=[O:115])[CH2:65][CH:66]([OH:114])[CH:67]([CH3:113])[CH:68]([C:102](=[CH:103][CH:104]2[CH2:105][CH:106]([OH:111])[CH:107]([OH:110])[CH2:108][CH2:109]2)[CH3:112])[O:69][C:70](=[O:101])[CH:71]2[CH2:72][CH2:73][CH2:74][CH2:75][N:76]2[C:77](=[O:100])[C:78](=[O:99])[C:79]2([OH:98])[CH:80]([CH3:97])[CH2:81][CH:82]([O:95][CH3:96])[CH:83]([CH:84]([O:92][CH3:93])[CH2:85][CH:86]([CH3:91])[CH2:87][C:88]([CH3:90])=[CH:89]1)[O:94]2.[Cu+2:128]>>[c:38]1([O:110][CH:107]2[CH:106]([OH:111])[CH2:105][CH:104]([CH:103]=[C:102]([CH:68]3[CH:67]([CH3:113])[CH:66]([OH:114])[CH2:65][C:64](=[O:115])[CH:63]([CH2:61][CH3:62])[CH:89]=[C:88]([CH3:90])[CH2:87][CH:86]([CH3:91])[CH2:85][CH:84]([O:92][CH3:93])[CH:83]4[CH:82]([O:95][CH3:96])[CH2:81][CH:80]([CH3:97])[C:79]([OH:98])([C:78](=[O:99])[C:77](=[O:100])[N:76]5[CH:71]([C:70](=[O:101])[O:69]3)[CH2:72][CH2:73][CH2:74][CH2:75]5)[O:94]4)[CH3:112])[CH2:109][CH2:108]2)[c:39]([O:52][SiH:53]([CH3:54])[CH3:55])[c:40]2[cH:41][cH:42][c:43]([C:48]([CH3:49])([CH3:50])[CH3:51])[cH:44][c:45]2[cH:46][cH:47]1

Participants

8

Reactant 7

HCID 175Acetate2×HCID 6344DichloromethaneHCID 6585Peracetic AcidHCID 8028TetrahydrofuranHCID 27099Cupric cationHCID 5720384517-Ethyl-1,14-dihydroxy-12-[2'(3",4"-dihydroxycyclohexyl)-1'-methylvinyl]-23,25-dimethoxy-13,19,21,27-tetramethyl-11,28-dioxa-4-azatricyclo[22.3.1.04,9]octacos-18-ene-2,3,10,16-tetraoneHCID 178504362HCID 178504362, compound

Product 1

HCID 178436249HCID 178436249, compound

Sources & evidence

ORD record
ord-d8453aab70944c27924a3ac322056a18
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Reaction notes

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