HRID319726

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID813

Potassium cation

K+

HCID8028

Tetrahydrofuran

C4H8O

HCID74506

Triphenylmethylphosphonium

C19H18P+

HCID4574913

未命名化合物

结构：CC(C)(C)[Si](C)(C)Oc1ccc(C2CCC(=O)CC2)c(O[Si](C)(C)C(C)(C)C)c1

HCID22337814

4-(2,4-Bis{[tert-butyl(dimethyl)silyl]oxy}phenyl)cyclohexan-1-one

C24H42O3Si2

PRODUCTS

生成物

结构：C=C1CCC(c2ccc(O[Si](C)(C)C(C)(C)C)cc2O[Si](C)(C)C(C)(C)C)CC1

HCID17946008

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-64d79c74cf3246d5961373d07ee3537c
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (8/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (8/10)

反应 SMILES

[Br-:36].[C:7]([CH3:8])([CH3:9])([CH3:10])[Si:11]([O:12][c:13]1[c:14]([CH:27]2[CH2:28][CH2:29][C:30](=[O:33])[CH2:31][CH2:32]2)[cH:15][cH:16][c:17]([O:19][Si:20]([CH3:21])([CH3:22])[C:23]([CH3:24])([CH3:25])[CH3:26])[cH:18]1)([CH3:34])[CH3:35].[CH3:1][C:2]([CH3:3])([O-:4])[CH3:5].[CH3:37][P+:38]([c:39]1[cH:40][cH:41][cH:42][cH:43][cH:44]1)([c:45]1[cH:46][cH:47][cH:48][cH:49][cH:50]1)[c:51]1[cH:52][cH:53][cH:54][cH:55][cH:56]1.[K+:6].[O:57]1[CH2:58][CH2:59][CH2:60][CH2:61]1>>[CH2:1]=[C:30]1[CH2:29][CH2:28][CH:27]([c:14]2[c:13]([O:12][Si:11]([C:7]([CH3:8])([CH3:9])[CH3:10])([CH3:34])[CH3:35])[cH:18][c:17]([O:19][Si:20]([CH3:21])([CH3:22])[C:23]([CH3:24])([CH3:25])[CH3:26])[cH:16][cH:15]2)[CH2:32][CH2:31]1