Potassium Cation → t-Butyl 2-(2-amino-4-thiazolyl)-2-[(1-(2-(trimethylsilyl)ethoxycarbonyl)-1-methylethoxy]imino]-acetate

HRID 321317Notes

Reaction equation

HRID 321317 reaction equation
[Br:17][C:18]([C:19](=[O:20])[O:21][CH2:22][CH2:23][Si:24]([CH3:25])([CH3:26])[CH3:27])([CH3:28])[CH3:29].[C:30](=[O:31])([O-:32])[O-:33].[CH3:37][N:38]([CH3:39])[CH:40]=[O:41].[K+:34].[K+:35].[NH2:1][c:2]1[s:3][cH:4][c:5]([C:7]([C:8](=[O:9])[O:10][C:11]([CH3:12])([CH3:13])[CH3:14])=[N:15][OH:16])[n:6]1.[OH2:36]>>[NH2:1][c:2]1[s:3][cH:4][c:5]([C:7]([C:8](=[O:9])[O:10][C:11]([CH3:12])([CH3:13])[CH3:14])=[N:15][O:16][C:18]([C:19](=[O:20])[O:21][CH2:22][CH2:23][Si:24]([CH3:25])([CH3:26])[CH3:27])([CH3:28])[CH3:29])[n:6]1

Participants

7

Reactant 6

HCID 813Potassium Cation2×HCID 962WaterHCID 6228DimethylformamideHCID 19660Carbonate IonHCID 15058060Propanoic acid, 2-bromo-2-methyl-, 2-(trimethylsilyl)ethyl esterHCID 139714452Tert-butyl 2-(2-amino-1,3-thiazol-4-yl)-2-hydroxyiminoacetate

Product 1

HCID 74015565t-Butyl 2-(2-amino-4-thiazolyl)-2-[(1-(2-(trimethylsilyl)ethoxycarbonyl)-1-methylethoxy]imino]-acetate

Sources & evidence

ORD record
ord-cfd29828ec8f4a1eb26af7647cb38f81
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Reaction notes

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