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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 324589Generated: October 26, 2026

methyl 2-(benzo[1,3]dioxol-5-yl)-4-(trifluoromethanesulfonyloxy)-2H-chromen-3-carboxylate → methyl 2-(benzo[1,3]dioxol-5-yl)-4-(4-methoxy-phenyl)-2H-chromen-3-carboxylate

https://huagongshe.com/reaction/324589

Reaction equation

Participants

RoleNameHCIDCharge
Reactantmethyl 2-(benzo[1,3]dioxol-5-yl)-4-(trifluoromethanesulfonyloxy)-2H-chromen-3-carboxylateHCID 11080999—
Reactant4-Methoxyphenyl boric acidHCID 14769994—
Productmethyl 2-(benzo[1,3]dioxol-5-yl)-4-(4-methoxy-phenyl)-2H-chromen-3-carboxylateHCID 11729397—

Reaction Steps

4-Methoxyphenyl boric acid and methyl 2-(benzo[1,3]dioxol-5-yl)-4-(trifluoromethanesulfonyloxy)-2H-chromen-3-carboxylate (III-5) synthesized from the compound (II-3) by a similar method as described in Reference Example 2 were reacted in a similar manner as described in Example 18 to give methyl 2-(benzo[1,3]dioxol-5-yl)-4-(4-methoxy-phenyl)-2H-chromen-3-carboxylate (Ia-4).

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS06218427B1
Source datasetuspto-grants-2001_04
ORD IDord-2b7fed30eece420e81192abb0f0f7426
Source noteuspto-grants-2001_04