HCID 67483535, compound → HCID 53963478, compound

HRID 324852Notes

Reaction equation

HRID 324852 reaction equation
[CH:1]([C:4]1[C:9]([C:10](OCC)=[O:11])=[C:8]([C:15]2[CH:20]=[CH:19][C:18]([Cl:21])=[CH:17][CH:16]=2)[C:7]([CH:22]=[CH:23][CH2:24][CH2:25][CH3:26])=[C:6]([CH:27]([CH3:29])[CH3:28])[N:5]=1)([CH3:3])[CH3:2]>C(OCC)(=O)C.CCCCCC>[CH:1]([C:4]1[C:9]([CH2:10][OH:11])=[C:8]([C:15]2[CH:16]=[CH:17][C:18]([Cl:21])=[CH:19][CH:20]=2)[C:7]([CH:22]=[CH:23][CH2:24][CH2:25][CH3:26])=[C:6]([CH:27]([CH3:28])[CH3:29])[N:5]=1)([CH3:3])[CH3:2]

Participants

3

Reactant 1

HCID 67483535HCID 67483535, compound

Product 1

HCID 53963478HCID 53963478, compound

Reagents, catalysts & solvents 1

HCID 21226206Ethyl acetate hexaneSolvent

Procedure

The title compound was prepared from the intermediate obtained in Step A by the procedure described in Example 125, Step F. 1H NMR (300 MHz, CDCl3) (reported as a 6:1 mixture of olefin isomers): δ 0.73-0.83 (m, 3 H), 1.10-1.40 (14 H), 1.91 (m, 2 H), 3.93 (m, 2 H), 4.39 (d, J=5.0 Hz, 2 H), 5.25-5.45 (m, 1 H), 5.98 (m, 1 H), 7.11 (m, 2 H), 7.35 (m, 2 H). Rf=0.36 (10% ethyl acetate/n-hexane).

Sources & evidence

ORD record
ord-ec2e823c12f24e2e82d80d2a18359b6f
Source dataset
uspto-grants-2001_04
Patent number
US06218431B1

Reaction notes

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