HCID 86756634, compound → HCID 73858735, compound

HRID 324863Notes

Reaction equation

HRID 324863 reaction equation
[CH:1]([C:4]1[C:9]([C:10](OCC)=[O:11])=[C:8]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][C:16]=2[C:21]#[CH:22])[C:7]([CH:23]=[CH:24][CH2:25][CH2:26][CH3:27])=[C:6]([CH:28]([CH3:30])[CH3:29])[N:5]=1)([CH3:3])[CH3:2]>C(OCC)(=O)C.CCCCCC>[CH:1]([C:4]1[C:9]([CH2:10][OH:11])=[C:8]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][C:16]=2[C:21]#[CH:22])[C:7]([CH:23]=[CH:24][CH2:25][CH2:26][CH3:27])=[C:6]([CH:28]([CH3:29])[CH3:30])[N:5]=1)([CH3:3])[CH3:2]

Participants

3

Reactant 1

HCID 86756634HCID 86756634, compound

Product 1

HCID 73858735HCID 73858735, compound

Reagents, catalysts & solvents 1

HCID 21226206Ethyl acetate hexaneSolvent

Procedure

The title compound was prepared from the intermediate obtained in Step D by the procedure described in Example 125, Step F. 1H NMR (300 MHz, CDCl3) (reported as a mixture of olefin isomers): δ 0.81 (t, J=7.4 Hz, 3 H), 1.0-1.40 (m, 15 H), 1.75 (m, 2 H), 2.98 (d, J=3.3 Hz, 1 H), 3.20-3.60 (m, 2 H), 4.20-4.50 (m, 2 H), 5.40 (m, 1 H), 6.0 (m, 1 H), 7.0-7.60 (m, 4 H). Rf=0.23 (10% ethyl acetate/n-hexane).

Sources & evidence

ORD record
ord-5c221cf435c046af983b13ff2f4f2b74
Source dataset
uspto-grants-2001_04
Patent number
US06218431B1

Reaction notes

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