HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium hydride → 2-[3-(2,6,6-Trimethyl-cyclohex-1-enyl)-acryloyl]-malonic acid bis-(3,7-dimethyl-oct6-enyl) ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium hydride | HCID 24758 | — |
| Reactant | Malonic acid bis-(3,7-dimethyl-oct-6-enyl) ester | HCID 54498946 | — |
| Reactant | 3-(2,6,6-Trimethyl-cyclohex-1-enyl)acryloyl chloride | HCID 54540111 | — |
| Reactant | HCID 73432804 | HCID 73432804 | — |
| Product | 2-[3-(2,6,6-Trimethyl-cyclohex-1-enyl)-acryloyl]-malonic acid bis-(3,7-dimethyl-oct6-enyl) ester | HCID 70167152 | — |
Reaction Steps
According to the procedure of Example 45, 2-[3-(2,6,6-trimethyl-cyclohex-1-enyl)-acryloyl]-malonic acid bis-3,7-dimethyl-oct-6-enyl) ester was prepared from malonic acid bis-(3,7-dimethyl-oct-6-enyl) ester, 3-(2,6,6-trimethyl-cyclohex-1-enyl)acryloyl chloride (Shimasaki et al., Chem. Pharm. Bull., 43 (1995) 1, 100-107) and sodium hydride.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06222062B1 |
| Source dataset | uspto-grants-2001_04 |
| ORD ID | ord-e9be92e0d2704ef0b56f1ebdc8ff72df |
| Source note | uspto-grants-2001_04 |