HRID325136

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID24758

Sodium hydride

HNa

结构：CC(C)=CCCC(C)CCOC(=O)CC(=O)OCCC(C)CCC=C(C)C

HCID54498946

未命名化合物

HCID54540111

未命名化合物

结构：CC1=C(C=CC(=O)C(C(=O)O)C(=O)O)C(C)(C)CCC1

HCID73432804

未命名化合物

PRODUCTS

生成物

结构：CC(C)=CCCC(C)CCOC(=O)C(C(=O)C=CC1=C(C)CCCC1(C)C)C(=O)OCCC(C)CCC=C(C)C

HCID70167152

未命名化合物

PROCEDURE

实验过程

According to the procedure of Example 45, 2-[3-(2,6,6-trimethyl-cyclohex-1-enyl)-acryloyl]-malonic acid bis-3,7-dimethyl-oct-6-enyl) ester was prepared from malonic acid bis-(3,7-dimethyl-oct-6-enyl) ester, 3-(2,6,6-trimethyl-cyclohex-1-enyl)acryloyl chloride (Shimasaki et al., Chem. Pharm. Bull., 43 (1995) 1, 100-107) and sodium hydride.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-e9be92e0d2704ef0b56f1ebdc8ff72df
来源数据集: uspto-grants-2001_04
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06222062B1
来源说明: uspto-grants-2001_04

反应 SMILES

[CH3:1][C:2]1[CH2:7][CH2:6][CH2:5][C:4]([CH3:9])([CH3:8])[C:3]=1[CH:10]=[CH:11][C:12](C(C(O)=O)C(O)=O)=[O:13].[CH3:21][CH:22]([CH2:42][CH2:43][CH:44]=[C:45]([CH3:47])[CH3:46])[CH2:23][CH2:24][O:25][C:26](=[O:41])[CH2:27][C:28]([O:30][CH2:31][CH2:32][CH:33]([CH3:40])[CH2:34][CH2:35][CH:36]=[C:37]([CH3:39])[CH3:38])=[O:29].CC1CCCC(C)(C)C=1C=CC(Cl)=O.[H-].[Na+]>>[CH3:21][CH:22]([CH2:42][CH2:43][CH:44]=[C:45]([CH3:47])[CH3:46])[CH2:23][CH2:24][O:25][C:26](=[O:41])[CH:27]([C:12](=[O:13])[CH:11]=[CH:10][C:3]1[C:4]([CH3:8])([CH3:9])[CH2:5][CH2:6][CH2:7][C:2]=1[CH3:1])[C:28]([O:30][CH2:31][CH2:32][CH:33]([CH3:40])[CH2:34][CH2:35][CH:36]=[C:37]([CH3:38])[CH3:39])=[O:29]