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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 325144Generated: October 31, 2026

Methane → Zirconocene Bisphenoxide

https://huagongshe.com/reaction/325144

Reaction equation

Participants

RoleNameHCIDCharge
ReactantMethaneHCID 297—
ReactantPhenolHCID 996—
ReactantBis(5-methylcyclopenta-1,3-diene);zirconium(2+)HCID 129652697—
SolventTolueneHCID 1140—
ProductZirconocene BisphenoxideHCID 131722530—

Reaction Steps

In a flask containing 50 ml of toluene, 1.988 millimoles of dimethyl zirconocene were dissolved. Successively under stirring 3.976 millimoles of phenol were added. The solution develops methane according to the reaction:

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS06222081B1
Source datasetuspto-grants-2001_04
ORD IDord-b912e0f94ec540e89a8f139fcd2bdc5f
Source noteuspto-grants-2001_04