Methane → Zirconocene Bisphenoxide

HRID 325144Notes

Reaction equation

HRID 325144 reaction equation
C[C-:2]1[CH:6]=[CH:5][CH:4]=[CH:3]1.[C-:7]1(C)[CH:11]=[CH:10][CH:9]=[CH:8]1.[Zr+2:13].[C:14]1([OH:20])[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.C>C1(C)C=CC=CC=1>[O-:20][C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.[O-:20][C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.[CH-:2]1[CH:6]=[CH:5][CH:4]=[CH:3]1.[CH-:7]1[CH:11]=[CH:10][CH:9]=[CH:8]1.[Zr+2:13]

Participants

5

Reactant 3

HCID 297MethaneHCID 996PhenolHCID 129652697Bis(5-methylcyclopenta-1,3-diene);zirconium(2+)

Product 1

HCID 131722530Zirconocene Bisphenoxide

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

In a flask containing 50 ml of toluene, 1.988 millimoles of dimethyl zirconocene were dissolved. Successively under stirring 3.976 millimoles of phenol were added. The solution develops methane according to the reaction:

Workup

  1. dissolutionwere dissolved
  2. additionwere added
  3. customto the reaction

Sources & evidence

ORD record
ord-b912e0f94ec540e89a8f139fcd2bdc5f
Source dataset
uspto-grants-2001_04
Patent number
US06222081B1

Reaction notes

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