2-Bromo-5-nitroanisole → HCID 10586298, compound

HRID 325203Notes

Reaction equation

HRID 325203 reaction equation
Br[C:2]1[CH:7]=[CH:6][C:5]([N+:8]([O-:10])=[O:9])=[CH:4][C:3]=1[O:11][CH3:12].[CH3:13][C:14]1[CH:15]=[C:16](B(O)O)[CH:17]=[CH:18][CH:19]=1>C([O-])(=O)C.[Pd+2].C([O-])(=O)C>[CH3:12][O:11][C:3]1[CH:4]=[C:5]([N+:8]([O-:10])=[O:9])[CH:6]=[CH:7][C:2]=1[C:18]1[CH:17]=[CH:16][CH:15]=[C:14]([CH3:13])[CH:19]=1

Participants

4

Reactant 2

HCID 1012932-Bromo-5-nitroanisoleHCID 27339503-Tolylboronic acid

Product 1

HCID 10586298HCID 10586298, compound

Reagents, catalysts & solvents 1

HCID 167845palladium(II) acetateCatalyst

Procedure

The title compound was prepared by reaction of 1-bromo-2-methoxy4-nitrobenzene with 3-methylphenylboronic acid in the presence of palladium acetate.

Sources & evidence

ORD record
ord-32a63f3674f8425ab73f392f1ae554f9
Source dataset
uspto-grants-2001_04
Patent number
US06221865B1

Reaction notes

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