HuagongsheHuagongshe Chemistry Print Report · For research reference only
Morpholine, 4-(1-cyclohexen-1-yl)- → 4-Cyclohexylmorpholine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Morpholine, 4-(1-cyclohexen-1-yl)- | HCID 69589 | — |
| Reactant | Phosphorous acid | HCID 107909 | — |
| Product | 4-Cyclohexylmorpholine | HCID 22938 | 91% |
Reaction Steps
1-morpholinocyclohexene (32.3 g; 0.19 mole) and phosphorous acid (15.9 g; 0.19 mole) were heated together with stirring to 100° and maintained for 1 hour. Dilution with water, basification with NaOH and extraction with chloroform gave 29.7 g (91% of N-cyclohexylmorpholine after evaporation of the solvent. ##STR17##
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04442286 |
| Source dataset | uspto-grants-1984_04 |
| ORD ID | ord-346fe52e682f44e9923b73f8fd2a4af4 |
| Source note | uspto-grants-1984_04 |