Hydrochloric Acid → HCID 86747408, compound

HRID 326544Notes

Reaction equation

HRID 326544 reaction equation
[CH3:1][N:2]([CH3:27])[CH2:3][CH2:4][CH2:5][N:6]([CH:24]([CH3:26])[CH3:25])[C:7](=[O:23])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22].[ClH:28]>C(OCC)C>[ClH:28].[CH3:27][N:2]([CH3:1])[CH2:3][CH2:4][CH2:5][N:6]([CH:24]([CH3:26])[CH3:25])[C:7](=[O:23])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]

Participants

4

Reactant 2

HCID 313Hydrochloric AcidHCID 9800155HCID 9800155, compound

Product 1

HCID 86747408HCID 86747408, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

To a solution of N,N-dimethyl-N'-(2-propyl)-N'-hexadecanoyl-1,3-propanediamine (0.20 g, 0.52 mmole) in diethyl ether was added an ethereal solution of hydrogen chloride. The reaction mixture was placed in the refrigerator overnight. The title compound (0.09 g, 45%) was collected by filtration as a white solid. mp. 80°-82° C. 1H NMR (300 MHz, CD3OD): δ0.65 to 0.69 (3H, bs), 1.080 (24H, bs), 11.37 to 1.40 (2H, m), 1.71 to 1.75 (2H, m), 2.21 to 2.24 (2H, m), 2.64 to 2.68 (6H, bs), 2.86 to 2.90 (2H, m), 3.06 to 3.10 (6H, bs), and 3.90 to 4.10 (1H, m). IR (KBr): 2915, 2848, 1649, and 1203 cm-1. Analysis calculated for C24H51ClN2O.1/4H2O: C, 68.05; H, 12.25; N, 6.61; Cl, 8.37. Found: C, 67.86; H, 12.11; N, 6.57; Cl, 8.24.

Workup

  1. customwas placed in the refrigerator overnight
  2. filtrationThe title compound (0.09 g, 45%) was collected by filtration as a white solid

Sources & evidence

ORD record
ord-528e115f6cb345fb91b8ab3a3e9f702b
Source dataset
uspto-grants-1993_12
Patent number
US05270310

Reaction notes

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