HCID 9859650, compound → HCID 22796915, compound

HRID 328553Notes

Reaction equation

HRID 328553 reaction equation
[C@@H:1]1([N:10]2[CH:17]=[CH:16][C:14](=[O:15])[NH:13][C:11]2=[O:12])[O:7][C@H:6]([CH2:8][OH:9])[C@H:4]([OH:5])[C@@H:2]1[OH:3]>O.[Rh]>[C@@H:1]1([N:10]2[CH2:17][CH2:16][C:14](=[O:15])[NH:13][C:11]2=[O:12])[O:7][C@H:6]([CH2:8][OH:9])[C@H:4]([OH:5])[C@@H:2]1[OH:3]

Participants

4

Reactant 1

HCID 9859650HCID 9859650, compound

Product 1

HCID 22796915HCID 22796915, compound

Reagents, catalysts & solvents 2

HCID 23948RhodiumCatalystHCID 962WaterSolvent

Procedure

In the manner given in Example 2A, 1-β-D-lyxofuranosyl-uracil [Fletcher et al., J. Am. Chem. Soc. 83, 1889 (1961)] was catalytically hydrogenated in water in the presence of rhodium on alumina catalyst to give 1-β-D-lyxofuranosyl-dihydrouracil.

Sources & evidence

ORD record
ord-43f259e0b99543fd9044cc0c9e51f3f5
Source dataset
uspto-grants-1977_04
Patent number
US04017606

Reaction notes

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