Glycine → Aluminum;bis(2-aminoacetate);hydroxide
Reaction equation
[NH2:1][CH2:2][C:3]([OH:5])=[O:4].[OH-:6].[Al+3:7].[OH-].[OH-].[I-].[Al+3].[I-].[I-].[I-].[NH2:15][CH2:16][C:17]([O-:19])=[O:18]>O>[NH2:1][CH2:2][C:3]([O-:5])=[O:4].[OH:6][Al+2:7].[NH2:15][CH2:16][C:17]([O-:19])=[O:18]Participants
7
Reactant 5
Product 1
Reagents, catalysts & solvents 1
Conditions
- Temperature
- 75 °C
Procedure
Monohydroxyaluminum glycinate was prepared by reacting 2 grams of glycine with 1.25 grams of aluminum hydroxide (28.8% Al) powder in 10 grams of water. The mixture was agitated at 75° C. for 1/2 hour. To 15 grams of a 331/2 solution of 5/6 basic aluminum iodide solution, Al2 (OH)5I (5.49% Al), was added 31.2 grams of a zirconyl iodide solution (6.3% Zr). The glycinate mixture was then added to the above solution while agitating at 80° C. for 30 minutes. The resultant clear solution was evaporated at 55° C. under a vacuum of 150 mm of Hg. The product contained 6.63% Al, 11.1% Zr, 48.3% I, and 11.1% glycine.
Workup
- stirringwhile agitating at 80° C. for 30 minutes
- customThe resultant clear solution was evaporated at 55° C. under a vacuum of 150 mm of Hg
Sources & evidence
- ORD record
- ord-8c42cf9d9ef844ce8138e0063f303b72
- Source dataset
- uspto-grants-1977_04
- Patent number
- US04017599
Reaction notes
Loading…