Nitric Acid → HCID 178423600, compound

HRID 328602Notes

Reaction equation

HRID 328602 reaction equation
[OH:1][C:2]1[C:11](=[O:12])[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][C:9]=2[CH3:13])[C:4](=[O:14])[CH:3]=1.[N+:15]([O-])([OH:17])=[O:16]>C(Cl)(Cl)Cl>[OH:1][C:2]1[C:11](=[O:12])[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][C:9]=2[CH3:13])[C:4](=[O:14])[C:3]=1[N+:15]([O-:17])=[O:16]

Participants

4

Reactant 2

HCID 944Nitric AcidHCID 178423599HCID 178423599, compound

Product 1

HCID 178423600HCID 178423600, compoundYield 43%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

A solution of 3-hydroxy-5-methyl-1,4-naphthoquinone (1.9g) in chloroform (200ml) was nitrated with fuming nitric acid according to example 1(a). A yield of 1.01g (43%) of material of m.p. 148°-149° C (d) was obtained. (Found; C, 56.69; H, 3.16; N, 5,73; C11H7NO5 requires; C, 56.66; H, 3.03; N, 6.01%).

Sources & evidence

ORD record
ord-a564b2b35f114dd18ff50e133f27c249
Source dataset
uspto-grants-1977_04
Patent number
US04017639

Reaction notes

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