HuagongsheHuagongshe Chemistry Print Report · For research reference only
tert-Butanol → HCID 178435351, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | tert-Butanol | HCID 6386 | — |
| Reactant | 6,7-Diethyl-3,4-dihydronaphthalen-1(2H)-one | HCID 12366399 | — |
| Reactant | Potassium tert-butoxide | HCID 23665647 | — |
| Product | HCID 178435351 | HCID 178435351 | 63% |
Reaction Steps
Autoxidation of 6,7-diethyl-1-tetralone (48g; 0.24 mole ) with potassium t-butoxide in t-butanol as described in example 8(b) afforded 34.60g (63%) of the title compound. Recrystallisation from aqueous ethanol in the presence of charcoal gave a yellow crystalline solid of m.p. 105°-109° C. (Found; C, 70.45; H, 6.10; C14H14O3 1/2H2O requires; C, 70.28; H, 6.32%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04017639 |
| Source dataset | uspto-grants-1977_04 |
| ORD ID | ord-0fe69cb552294af6be42deb9d0acceb6 |
| Source note | uspto-grants-1977_04 |