Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Nitromethane | HCID 6375 | — |
| Reactant | Sodium | HCID 5360545 | — |
| Reactant | Sodium Methoxide | HCID 10942334 | — |
| Reactant | 10-Undecenoic acid, 9-oxo-, methyl ester | HCID 11127586 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | HCID 85527109 | HCID 85527109 | — |
Reaction Steps
Nitromethane (12.8 g; 0.21 mole) is added dropwise to a solution of sodium methoxide, prepared from sodium (4.6 g; 0.2 mole) and methanol (200 ml), at 0°-5° C. The solution is cooled to -20° C. and 9-keto-10-undecanoic acid, methyl ester (III) (21.2 g; 0.1 mole) is added dropwise into the solution over 5 hours.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04894473 |
|---|
| Source dataset | uspto-grants-1990_01 |
|---|
| ORD ID | ord-dc22809165f84ff6a2e8e417429b1de7 |
|---|
| Source note | uspto-grants-1990_01 |
|---|
