Nitromethane → HCID 85527109, compound

HRID 330101Notes

Reaction equation

HRID 330101 reaction equation
[N+:1]([CH3:4])([O-:3])=[O:2].C[O-].[Na+].[Na].[O:9]=[C:10]([CH:22]=[CH2:23])[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][C:18]([O:20][CH3:21])=[O:19]>CO>[O:9]=[C:10]([CH2:22][CH2:23][CH2:4][N+:1]([O-:3])=[O:2])[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][C:18]([O:20][CH3:21])=[O:19]

Participants

6

Reactant 4

HCID 6375NitromethaneHCID 5360545SodiumHCID 10942334Sodium MethoxideHCID 1112758610-Undecenoic acid, 9-oxo-, methyl ester

Product 1

HCID 85527109HCID 85527109, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Conditions

Temperature
-20 °C

Procedure

Nitromethane (12.8 g; 0.21 mole) is added dropwise to a solution of sodium methoxide, prepared from sodium (4.6 g; 0.2 mole) and methanol (200 ml), at 0°-5° C. The solution is cooled to -20° C. and 9-keto-10-undecanoic acid, methyl ester (III) (21.2 g; 0.1 mole) is added dropwise into the solution over 5 hours.

Sources & evidence

ORD record
ord-dc22809165f84ff6a2e8e417429b1de7
Source dataset
uspto-grants-1990_01
Patent number
US04894473

Reaction notes

Loading…