HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phthalic Anhydride → HCID 13593166, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phthalic Anhydride | HCID 6811 | — |
| Reactant | Triethylborane | HCID 7357 | — |
| Reactant | Benzoic acid, 2-[4-(1,1-dimethylpropyl)benzoyl]- | HCID 116561 | — |
| Reactant | Aluminum(III) Chloride | HCID 6451240 | — |
| Solvent | tert-Amylbenzene | HCID 16295 | — |
| Product | HCID 13593166 | HCID 13593166 | — |
Reaction Steps
74 g (0.5 mole) of phthalic anhydride and 134 g (1.10 moles) of AlCl3 were reacted with 20 g (0.2 mole) of triethylboron in 74 g of tert-amylbenzene for 8 hours, as described in Example 1. After the mixture had been worked up in a conventional manner, 127 g (86% of theory) of a mixture of 2-(4'-tert-amylbenzoyl)-benzoic acid and 2-(4'-sec-isoamylbenzoyl)-benzoic acid (tertiary/secondary ratio=60:40) were obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04895984 |
| Source dataset | uspto-grants-1990_01 |
| ORD ID | ord-7c554244106245318294c00cf237356d |
| Source note | uspto-grants-1990_01 |