HRID342340

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CCCCCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCCCC)OC(=O)CCCCCCCCCCCCCCCCC

HCID11146

Glyceryl tristearate

C57H110O6

3 次

PRODUCTS

生成物

$结构：CCCCCCCC/C=C\CCCCCCCC(=O)O$

HCID445639

Oleic acid

C18H34O2

收率 30%

$结构：CCCCCCCC/C=C\CCCCCCCCCCCC(=O)O$

HCID5281116

Erucic acid

C22H42O2

收率 62%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID180

Acetone

C3H6O

PROCEDURE

实验过程

A spread was prepared in a manner similar as described in Example I, except that the mixture to be interesterified comprised 57 parts of the palm oil stearin and 43 parts of the palmkernel stearin. The margarine fat blend comprised 8% of the stearin fraction obtained from fractionation in acetone of the randomly interesterified mixture, 62% low erucic acid rapeseed oil and 30% of a high oleic acid residue containing variety of linseed oil. A very good product was obtained.

WORKUP

后处理

customA spread was prepared in a manner similar

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-c3acdc9d01fa46238449b3d3c0b1fee6
来源数据集: uspto-grants-1999_01
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05858445
来源说明: uspto-grants-1999_01

反应 SMILES

[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][C:18]([O:20]CC([O:44][C:45]([CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH2:57][CH2:58][CH2:59][CH2:60][CH2:61][CH2:62][CH3:63])=[O:46])COC(CCCCCCCCCCCCCCCCC)=O)=[O:19]>CC(C)=O>[C:45]([OH:44])(=[O:46])[CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH2:57]/[CH:58]=[CH:59]\[CH2:60][CH2:61][CH2:62][CH2:63][CH2:1][CH2:2][CH2:3][CH3:4].[C:18]([OH:20])(=[O:19])[CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11]/[CH:10]=[CH:9]\[CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]