HCID 54559733, compound → HCID 54539163, compound

HRID 342786Notes

Reaction equation

HRID 342786 reaction equation
[CH2:1]([C:4]1[C:9]([O:10][CH2:11][C:12]([CH2:14][CH3:15])=[O:13])=[CH:8][CH:7]=[CH:6][C:5]=1[OH:16])[CH:2]=[CH2:3]>C(OCC)(=O)C.[Pd]>[CH2:1]([C:4]1[C:9]([O:10][CH2:11][C:12]([CH2:14][CH3:15])=[O:13])=[CH:8][CH:7]=[CH:6][C:5]=1[OH:16])[CH2:2][CH3:3]

Participants

4

Reactant 1

HCID 54559733HCID 54559733, compound

Product 1

HCID 54539163HCID 54539163, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 8857Ethyl AcetateSolvent

Procedure

A solution of 2-allyl-3-(2-ethyl-2-oxoethoxy)phenol (480 mg) in ethyl acetate (25 mL) was treated with 10% palladium (75 mg) on carbon catalyst. The mixture was shaken under a hydrogen atmosphere (40 psi) for two hours. The mixture was filtered through Celite and concentrated to get the title compound.

Workup

  1. filtrationThe mixture was filtered through Celite
  2. concentrationconcentrated

Sources & evidence

ORD record
ord-ffd1c2729de6466cb325d496cd79fdf3
Source dataset
uspto-grants-1999_01
Patent number
US05859051

Reaction notes

Loading…