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HRID34297

反应详情

EQUATION

反应方程式

HRID 34297 的结构方程式

REACTANTS

反应物

3
结构：Cl
HCID313

Hydrochloric Acid

ClH

结构：CC(=O)[O-].O.[Na+]
HCID23681166

Sodium acetate hydrate (1:1:1)

C2H5NaO3

结构：CC[C@@H](C(=O)[C@@H](C)[C@@H](O)[C@@H](C)[C@H]1O[C@@H](CC(=O)OO)[C@H](C)C[C@@H]1C)[C@H]1O[C@](C)([C@]2(O)O[C@](CC)([C@@H](O)CC)C[C@H]2C)C[C@@H]1C.[Na]
HCID86741790

未命名化合物

2 次

PRODUCTS

生成物

1
结构：CC[C@@H](C(=O)[C@@H](C)[C@@H](O)[C@@H](C)[C@H]1O[C@@H](CC(=O)OO)[C@H](C)C[C@@H]1C)[C@H]1O[C@](C)([C@]2(O)O[C@](CC)([C@@H](O)CC)C[C@H]2C)C[C@@H]1C
HCID44567051

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：CC(=O)[O-].CC(=O)[O-].O.[Zn+2]
催化剂HCID20271390

未命名化合物

结构：CCO
溶剂HCID702

Ethanol

C2H6O

2 次

PROCEDURE

实验过程

3.9 g sodium lysocellin @(0.006 moles) and 1.4 g zinc acetate hydrate [Zn(Ac)2.2H2O] @(.006 mole) were mixed together in 30 ml denatured ethanol (3A). The sodium lysocellin was first suspended in the ethanol and stirred, and the sodium acetate hydrate was added, and the suspension stirred at room temperature until everything was dissolved. The pH was then adjusted to a range of 2-4, with 37% HCl. Stirring was continued for 20-30 minutes until precipitation of a birefringent material started. Precipitation was continued by adding water dropwise (holding pH at 4) until about 60 ml of water was added. The resulting crystalling precipitate of the free acid of lysocellin was isolated and dried. The resulting free acid of lysocellin comprised birefringent crystals.

WORKUP

后处理

  1. stirringthe suspension stirred at room temperature until everything
  2. dissolutionwas dissolved
  3. stirringStirring
  4. customwas continued for 20-30 minutes until precipitation of a birefringent material
  5. customPrecipitation
  6. additionby adding water dropwise (holding pH at 4) until about 60 ml of water
  7. additionwas added