Diethyl Ether → HCID 86745121, compound

HRID 344766Notes

Reaction equation

HRID 344766 reaction equation
[OH:1][CH:2]([CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16]/[CH:17]=[CH:18]\[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])[CH2:3][CH2:4][CH2:5][NH:6][C:7](=[O:9])[CH3:8].[Cr](Cl)([O-])(=O)=O.[NH+]1C=CC=CC=1.CCOCC>ClCCl>[O:1]=[C:2]([CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16]/[CH:17]=[CH:18]\[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])[CH2:3][CH2:4][CH2:5][NH:6][C:7](=[O:9])[CH3:8]

Participants

5

Reactant 3

HCID 3283Diethyl EtherHCID 86745122HCID 86745122, compoundHCID 178418287HCID 178418287, compound

Product 1

HCID 86745121HCID 86745121, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

A 0.5 g portion of N-(4-hydroxy-12(Z)-eicosenyl)-acetamide was stirred with 0.44 g of pyridinium chlorochromate in 15 ml of dichloromethane for 2 hours. This mixture was poured into 50 ml of ether and filtered through hydrous magnesium silicate. The filtrate was evaporated giving 0.24 g of the desired product as a pale yellow solid, mp 51-52° C.

Workup

  1. filtrationfiltered through hydrous magnesium silicate
  2. customThe filtrate was evaporated

Sources & evidence

ORD record
ord-f5b2d5c3b9094673b6432afb4dbfe418
Source dataset
uspto-grants-1991_10
Patent number
US05053426

Reaction notes

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