HuagongsheHuagongshe Chemistry Print Report · For research reference only
m-Chloroperbenzoic acid → 4-(diethylphosphonomethyl)pyridine-N-oxide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | m-Chloroperbenzoic acid | HCID 70297 | — |
| Reactant | 4-(Diethoxyphosphorylmethyl)pyridine | HCID 10078602 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | 4-(diethylphosphonomethyl)pyridine-N-oxide | HCID 14541437 | — |
Reaction Steps
The starting material is prepared as follows: A mixture of 2.2 g of 4-(diethylphosphonomethyl)pyridine [Roczniki Chem. 38, (4), 625 (1964); Chem. Abst. 61, 10703], 2.2 g of m-chloroperbenzoic acid and 30 ml of chloroform is stirred at room temperature for 16 hours. The solvent is removed in vacuo and water is added. After washing the aqueous layer with ether, the water is removed in vacuo to afford 4-(diethylphosphonomethyl)pyridine-N-oxide.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05057506 |
| Source dataset | uspto-grants-1991_10 |
| ORD ID | ord-3ccf6e46f6d14bbc8bfbce07e66e9e4d |
| Source note | uspto-grants-1991_10 |