Methanol → HCID 54196315、化合物

HRID 345872ノート

反応式

HRID 345872 の反応式
Br[CH:2]([CH2:8][CH2:9][CH2:10]Br)[C:3]([O:5][CH2:6][CH3:7])=[O:4].C(=O)([O-])[O-].[K+].[K+].[CH2:18]([NH2:30])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29].CO>C(O)C>[CH2:6]([O:5][C:3](=[O:4])[C@@H:2]1[CH2:8][CH2:9][CH2:10][N:30]1[CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])[CH3:7]

参加物

6

反応物 4

HCID 887MethanolHCID 11430Potassium CarbonateHCID 13583DodecylamineHCID 11022534Ethyl 2,5-dibromopentanoate

生成物 1

HCID 54196315HCID 54196315、化合物

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

実験手順

In 150 ml of ethanol was dissolved 22.8 g of ethyl 2,5-dibromovalerate, and 15 g of potassium carbonate was suspended in the solution. To the suspension was added dropwise a methanolic solution of 18.5 g of laurylamine under ice-cooling. After the addition, the reaction mixture was allowed by react at a refluxing temperature of methanol for 5 hours to obtain N-dodecylproline ethyl ester.

後処理

  1. temperaturecooling
  2. additionAfter the addition

出典と根拠

ORDレコード
ord-133022ee30e24a839e4911617c6226af
出典データセット
uspto-grants-1991_10
特許番号
US05059628

反応ノート

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