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HRID351892

反应详情

EQUATION

反应方程式

HRID 351892 的结构方程式

REACTANTS

反应物

3
结构：O=C(OO)c1cccc(Cl)c1
HCID70297

Benzenecarboperoxoic acid, 3-chloro-

C7H5ClO3

结构：CS(=O)c1ccc(N2C[C@@H](CN=[N+]=[N-])OC2=O)cc1F
HCID22966213

未命名化合物

结构：[N-]=[N+]=NC[C@@H]1CN(c2ccc(SCCF)c(F)c2)C(=O)O1
HCID86586392

未命名化合物

PRODUCTS

生成物

1
结构：[N-]=[N+]=NC[C@@H]1CN(c2ccc(S(=O)CCF)c(F)c2)C(=O)O1
HCID86586393

未命名化合物

PROCEDURE

实验过程

This compound was prepared analogously to the synthesis of 5-(S)-azidomethyl-3-[4′-methylsulfinyl-3′-fluorophenyl]oxazolidine-2-one from 5-(S)-azidomethyl-3-[4′-(2″-fluoroethyl)thio-3′-fluorophenyl]oxazolidine-2-one (0.280 g, 0.891 mmol) and m-chloroperoxybenzoic acid (77%, 0.200 g, 0.891 mmol). Yield 0.280 g (95%). MS (m/z): [M+H]+=331.