Hydrochloric Acid → 2-Chloro-1,3,5-triaminobenzene

HRID 353401Notes

Reaction equation

[Cl:1][C:2]1[C:7]([N+:8]([O-])=O)=[CH:6][C:5]([N+:11]([O-])=O)=[CH:4][C:3]=1[N+:14]([O-])=O.[Sn].Cl>>[Cl:1][C:2]1[C:7]([NH2:8])=[CH:6][C:5]([NH2:11])=[CH:4][C:3]=1[NH2:14]

Participants

Reactant 3

HCID 313Hydrochloric Acid

HCID 6953Picryl Chloride

HCID 5352426Tin atom

Product 1

HCID 227088982-Chloro-1,3,5-triaminobenzene

Procedure

The nitro groups of 2-chloro-1,3,5-trinitrobenzene (1) are reduced by reaction with tin and hydrochloric acid to yield 2-chloro-1,3,5-triaminobenzene (2).

Sources & evidence

ORD record: ord-d169a7f43eaa4894a417d3cc2070d2cb
Source dataset: uspto-grants-2004_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06751290B2

Reaction notes

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