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HRID354036

反应详情

EQUATION

反应方程式

HRID 354036 的结构方程式

REACTANTS

反应物

3
结构：c1c[nH]cn1
HCID795

Imidazole

C3H4N2

结构：C[SiH](C)C(C)(C)C
HCID5072427

tert-Butyldimethylsilane

C6H16Si

结构：Cc1oc(=O)oc1CO
HCID10510878

4-(hydroxymethyl)-5-methyl-1,3-dioxol-2-one

C5H6O4

PRODUCTS

生成物

1
结构：Cc1oc(=O)oc1CO[Si](C)(C)C(C)(C)C
HCID23511477

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CN(C)C=O
溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

PROCEDURE

实验过程

A solution of 5-methyl-4-hydroxymethyl-2-oxo-1,3-dioxolene (1 mmole) in DMF was treated with tert-butyldimethylsilane (1.2 mmole) and imidazole (2.2 mmole) at 25° C. for 24 h. Extraction and chromatography gave 5-methyl-4-tert-butyldimethylsilyloxymethyl-2-oxo-1,3-dioxolene.

WORKUP

后处理

  1. extractionExtraction and chromatography