HRID354755

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID10898

2-Bromo-1-ethanol

C2H5BrO

结构：CN1C(=O)C(C)(C)N=C(c2ccccc2F)c2cc([N+](=O)[O-])ccc21

HCID20506156

未命名化合物

结构：CC1(C)N=C(c2ccccc2Cl)c2cc([N+](=O)[O-])ccc2N(CCO)C1=O

HCID20506179

未命名化合物

PRODUCTS

生成物

结构：CC1(C)N=C(c2ccccc2Cl)c2cc([N+](=O)[O-])ccc2NC1=O

HCID20506168

5-(o-chlorophenyl)-1,3-dihydro-3,3-dimethyl-7-nitro-2H-1,4-benzodiazepin-2-one

C17H14ClN3O3

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID21584099

Diethylether hexane

C10H24O

PROCEDURE

实验过程

From 25 g (0.073 mol) of 5-(o-chlorophenyl)-1,3-dihydro-3,3-dimethyl-7-nitro-2H-1,4-benzodiazepin-2-one and 2-bromoethanol there is obtained, in analogy to the details in paragraph (c) of Example 1, with a reaction period of 7 days, 5-(o-chlorophenyl)-1,3-dihydro-1-(2-hydroxyethyl)-3,3-dimethyl-7-nitro-2H-1,4-benzodiazepin-2-one of melting point 124°-125° (ether/n-hexane).