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HRID355350

反应详情

EQUATION

反应方程式

HRID 355350 的结构方程式

REACTANTS

反应物

2
结构：O=Cc1ccc2sccc2c1
HCID139097

Benzo(b)thiophene-5-carboxaldehyde

C9H6OS

结构：CC(=O)OC[C@H]1O[C@H](O[C@H]2[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](Oc3cccc(O)c3C(C)=O)O[C@@H]2COC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@@H]1OC(C)=O
HCID10605212

未命名化合物

PRODUCTS

生成物

1
结构：O=C(CCc1ccc2sccc2c1)c1c(O)cccc1O[C@@H]1O[C@H](CO)[C@@H](O[C@H]2O[C@H](CO)[C@@H](O)[C@H](O)[C@H]2O)[C@H](O)[C@H]1O
HCID18666457

未命名化合物

收率 51.8%

PROCEDURE

实验过程

2' -[2,3,6-Tri-O-acetyl-4-O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-β-D-glucopyranosyloxy]-6'-hydroxyacetophenone (1541 mg) and benzo[b]thiophene-5-carbaldehyde (389 mg) are treated in the same manner as in Example 1 to give 2'-[4-O-(α-D-glucopyranosyl)-β-D-glucopyranosyloxy]-6'-hydroxy-3-(5-benzo[b]thienyl)propiophenone (645 mg).