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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 355350Erstellt: 25. Oktober 2026

Benzo(b)thiophene-5-carboxaldehyde → 2'-[4-O-(alpha-D-glucopyranosyl)-beta-D-glucopyranosyloxy]-6'-hydroxy-3-(5-benzo[b]thienyl)propiophenone

https://huagongshe.com/reaction/355350

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
EduktBenzo(b)thiophene-5-carboxaldehydeHCID 139097—
Edukt2'-[2,3,6-Tri-O-acetyl-4-O-(2,3,4,6-tetra-O-acetyl-alpha-D-glucopyranosyl)-beta-D-glucopyranosyloxy]-6'-hydroxyacetophenoneHCID 10605212—
Produkt2'-[4-O-(alpha-D-glucopyranosyl)-beta-D-glucopyranosyloxy]-6'-hydroxy-3-(5-benzo[b]thienyl)propiophenoneHCID 1866645751,8%

Reaktionsschritte

2' -[2,3,6-Tri-O-acetyl-4-O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-β-D-glucopyranosyloxy]-6'-hydroxyacetophenone (1541 mg) and benzo[b]thiophene-5-carbaldehyde (389 mg) are treated in the same manner as in Example 1 to give 2'-[4-O-(α-D-glucopyranosyl)-β-D-glucopyranosyloxy]-6'-hydroxy-3-(5-benzo[b]thienyl)propiophenone (645 mg).

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS05830873
Quelldatensatzuspto-grants-1998_11
ORD IDord-6c92cb5b82d24d96aa1ebc26b0cd1ee7
Quellennotizuspto-grants-1998_11