Tributylvinyltin → HCID 18940943, compound

HRID 356038Notes

Reaction equation

HRID 356038 reaction equation
[C:1]([N:4]1[C:12]2[C:7](=[CH:8][C:9](I)=[C:10]([Cl:13])[CH:11]=2)[CH2:6][CH2:5]1)(=[O:3])[CH3:2].[CH:15]([Sn](CCCC)(CCCC)CCCC)=[CH2:16]>>[C:1]([N:4]1[C:12]2[C:7](=[CH:8][C:9]([CH:15]=[CH2:16])=[C:10]([Cl:13])[CH:11]=2)[CH2:6][CH2:5]1)(=[O:3])[CH3:2]

Participants

3

Reactant 2

HCID 81998TributylvinyltinHCID 18940886HCID 18940886, compound

Product 1

HCID 18940943HCID 18940943, compound

Procedure

1-Acetyl-6-chloro-5-iodoindoline (D60) (0.19 g, 0.6 mmol) was treated with vinyl tributyltin as in the method developed by Stille (A. M. Echavarren and J. K. Stille, J. Am. Chem. Soc., 1987, 109, 5478) to give the title compound (0.13 g) as a brown oil which was used without further purification.

Sources & evidence

ORD record
ord-5244586881274912802ac99e6c10b71e
Source dataset
uspto-grants-1998_11
Patent number
US05834494

Reaction notes

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