3,5-Di-tert-butylcatechol → 1,2-Bis-(2-cyanophenoxy)-3,5-di-tert-butylbenzene

HRID 356235Notes

Reaction equation

F[C:2]1[CH:9]=[CH:8][CH:7]=[CH:6][C:3]=1[C:4]#[N:5].[OH:10][C:11]1[CH:16]=[C:15]([C:17]([CH3:20])([CH3:19])[CH3:18])[CH:14]=[C:13]([C:21]([CH3:24])([CH3:23])[CH3:22])[C:12]=1[OH:25]>>[C:4]([C:3]1[CH:6]=[CH:7][CH:8]=[CH:9][C:2]=1[O:10][C:11]1[CH:16]=[C:15]([C:17]([CH3:18])([CH3:19])[CH3:20])[CH:14]=[C:13]([C:21]([CH3:24])([CH3:23])[CH3:22])[C:12]=1[O:25][C:2]1[CH:9]=[CH:8][CH:7]=[CH:6][C:3]=1[C:4]#[N:5])#[N:5]

Participants

Reactant 2

HCID 660993,5-Di-tert-butylcatechol

HCID 678552-Fluorobenzonitrile

Product 1

HCID 218407351,2-Bis-(2-cyanophenoxy)-3,5-di-tert-butylbenzeneYield 90.1%

Procedure

The compound 1,2-bis-(2-cyanophenoxy)-3,5-di-tert-butylbenzene was prepared, according to the procedure of Example 1, by reacting 2-fluorobenzonitrile with 1,2-dihydroxy-3,5-di-tert-butyl benzene. The product was recrystallized from ethanol to give a 90.1% yield of the title compound with the formula: ##STR11##

Workup

customThe compound 1,2-bis-(2-cyanophenoxy)-3,5-di-tert-butylbenzene was prepared
customThe product was recrystallized from ethanol

Sources & evidence

ORD record: ord-1aa055fae81845aaaf05c63b6ad41d2d
Source dataset: uspto-grants-1998_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05834620

Reaction notes

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