Acetone → HCID 54567841, compound

HRID 356453Notes

Reaction equation

HRID 356453 reaction equation
[CH2:1]([O:8][C:9]1[CH:10]=[C:11]([CH:14]=[CH:15][CH:16]=1)[CH:12]=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH3:17][C:18]([CH3:20])=[O:19]>CCO>[CH2:1]([O:8][C:9]1[CH:10]=[C:11]([CH:12]=[CH:10][C:9](=[O:8])[CH:16]=[CH:15][C:14]2[CH:11]=[CH:12][CH:20]=[C:18]([O:19][CH2:1][C:2]3[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=3)[CH:17]=2)[CH:14]=[CH:15][CH:16]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

4

Reactant 2

HCID 180AcetoneHCID 743423-Benzyloxybenzaldehyde

Product 1

HCID 54567841HCID 54567841, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

The title compound was prepared as described in General Method 2 using 5.03 g (23.7 mmol) of 3-benzyloxy-benzaldehyde, 150 mL of EtOH, 0.65 mL (11.2 mmol) of acetone, and 0.31 g of Ba(OH)2.(H2O)8. The mixture was heated at room temperature overnight and filtered to give the title compound. 1H NMR (CDCl3) δ 5.08 (s, 4 H), 7.03-7.07 (m, 4 H), 7.22-7.47 (m, 16 H), 7.69 (d, 2 H).

Workup

  1. customThe title compound was prepared
  2. filtrationfiltered

Sources & evidence

ORD record
ord-782d60ad8d7e44daa6114cf9ca12bffd
Source dataset
uspto-grants-1998_11
Patent number
US05834506

Reaction notes

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