(3-Bromopropyl)benzene → HCID 86753002, compound

HRID 357840Notes

Reaction equation

HRID 357840 reaction equation
Br[CH2:2][CH2:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.[S:11]([C:15]1[CH:21]=[CH:20][C:18]([CH3:19])=[CH:17][CH:16]=1)([O-:14])(=[O:13])=[S:12].[K+]>C(O)C>[C:5]1([CH2:4][CH2:3][CH2:2][O:14][S:11]([C:15]2[CH:21]=[CH:20][C:18]([CH3:19])=[CH:17][CH:16]=2)(=[S:12])=[O:13])[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1

Participants

4

Reactant 2

HCID 12503(3-Bromopropyl)benzeneHCID 23662126Benzenesulfonothioic acid, 4-methyl-, potassium salt

Product 1

HCID 86753002HCID 86753002, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

The title compound was prepared as described in General Method 2 using 1-bromo-3-phenylpropane (0.044 mmol), potassium thiotosylate (0.044 mmol) and absolute ethanol (125 mL) to give an oil which was used without purification. 1H NMR (CDCl3) δ 1.95 (quint., 2 H), 2.459 (s, 3 H), 2.63 (t, 2 H), 2.95 (t, 2 H), 7.0-7.4 (m, 8 H), 7.7 (d, 2 H).

Workup

  1. customto give an oil which
  2. customwas used without purification

Sources & evidence

ORD record
ord-f8d73daa2a704338a9e533a0f3acd15a
Source dataset
uspto-grants-1998_11
Patent number
US05840751

Reaction notes

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