Acrolein → HCID 13088566, compound

HRID 358017Notes

Reaction equation

HRID 358017 reaction equation
[C:1]([CH:5]=[CH:6][CH:7]=[CH2:8])([CH3:4])([CH3:3])[CH3:2].[CH:9]([CH:11]=[CH2:12])=[O:10].C(C1CCC(C=O)CC=1)(C)(C)C>>[C:1]([C:5]1[CH2:12][CH:11]([CH:9]=[O:10])[CH2:8][CH2:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2]

Participants

4

Reactant 3

HCID 7847AcroleinHCID 1420695,5-Dimethyl-1,3-hexadieneHCID 13088567HCID 13088567, compound

Product 1

HCID 13088566HCID 13088566, compoundYield 30%

Procedure

Molar amounts of tert.-butylbutadiene and acrolein are refluxed for 6-8 hours. A mixture of about 70% of 4-tert.-butyl-cyclohex-3-ene-1-carboxaldehyde and about 30% of 3-tert.-butyl-cyclohex-3-ene-1-carboxaldehyde is obtained in a yield of about 80%. Boiling point: 112° C./28 mbar.

Sources & evidence

ORD record
ord-9ca5366014a948e9a3738c128a37ac97
Source dataset
uspto-grants-1984_08
Patent number
US04464370

Reaction notes

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