Formaldehyde → HCID 131713657, compound

HRID 358200Notes

Reaction equation

HRID 358200 reaction equation
[CH2:1]([NH:5][CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4].[CH2:10]=O.[CH3:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][SH:24]>C(O)(C)C>[CH2:1]([N:5]([CH2:10][S:24][CH2:23][CH2:22][CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH3:12])[CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4]

Participants

5

Reactant 3

HCID 712FormaldehydeHCID 8148DibutylamineHCID 81951-Dodecanethiol

Product 1

HCID 131713657HCID 131713657, compound

Reagents, catalysts & solvents 1

HCID 3776IsopropanolSolvent

Procedure

Dibutylamine (129 gms.; 0.1 mole) was dissolved in isopropanol (25 gms). The solution was cooled in an ice bath and stirred during addition of aqueous formaldehyde (9 ml of 37% solution; 0.11 mole). To the solution there was added dodecylthiol (20.2 gms; 0.1 mole) in one portion and the mixture was stirred for 1 hour at room temperature. Di(butyl) aminomethyl dodecylsulfide was obtained as a clear, homogeneous solution.

Workup

  1. temperatureThe solution was cooled in an ice bath

Sources & evidence

ORD record
ord-ce4552a8cada45d59311dee323e2c6f2
Source dataset
uspto-grants-1984_08
Patent number
US04465620

Reaction notes

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