HRID358925

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：Nc1c([N+](=O)[O-])c(N)c([N+](=O)[O-])c(N)c1[N+](=O)[O-]

HCID18286

1,3,5-Benzenetriamine, 2,4,6-trinitro-

C6H6N6O6

2 次

HCID24386

Thionyl chloride

Cl2OS

结构：COc1c([N+](=O)[O-])c(Cl)c([N+](=O)[O-])c(Cl)c1[N+](=O)[O-]

HCID14794057

1,3-Dichloro-5-methoxy-2,4,6-trinitrobenzene

C7H3Cl2N3O7

PRODUCTS

生成物

结构：O=[N+]([O-])c1c(Cl)c([N+](=O)[O-])c(Cl)c([N+](=O)[O-])c1Cl

HCID17518

1,3,5-Trichloro-2,4,6-trinitrobenzene

C6Cl3N3O6

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

PROCEDURE

实验过程

Preparation of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) from 3,5-dichloroanisole. Nitration of 3,5-dichloroanisole under relatively mild conditions gave 3,5-dichloro-2,4,6-trinitroanisole in high yield and purity. Ammonolysis of this latter compound gave the desired TATB. Another route to TATB was through the treatment of the 3,5-dichloro-2,4,6-trinitroanisole with thionyl chloride and dimethylformamide to yield 1,3,5-trichloro-2,4,6-trinitrobenzene. Ammonolysis of this product produced TATB.

WORKUP

后处理

customin high yield