HCID 14230339, compound → HCID 14230327, compound

HRID 359048Notes

Reaction equation

HRID 359048 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([CH:8]([N:17]2[CH:21]=[CH:20][N:19]=[CH:18]2)[CH:9]([OH:16])[C:10]([CH3:15])([CH3:14])[CH2:11][CH2:12][CH3:13])[CH:5]=[CH:6][CH:7]=1>[Pt]>[Cl:1][C:2]1[CH:3]=[C:4]([CH:8]([N:17]2[CH:21]=[CH:20][N:19]=[CH:18]2)[CH:9]([OH:16])[C:10]([CH3:15])([CH3:14])[CH2:11][CH:12]=[CH2:13])[CH:5]=[CH:6][CH:7]=1

Participants

3

Reactant 1

HCID 14230339HCID 14230339, compound

Product 1

HCID 14230327HCID 14230327, compound

Reagents, catalysts & solvents 1

HCID 23939PlatinumCatalyst

Procedure

In the same fashion as described in Example 26, 1.43 g of 1-(3-chlorophenyl)-3,3-dimethyl-1-(1-imidazolyl)-2-hexanol of melting point 97° C. were obtained through hydrogenation on a 5 mmol scale of 1-(3-chlorophenyl)-3,3-dimethyl-1-(1-imidazolyl)-5-hexen-2-ol (compound according to Example 2) with 200 mg of sulfidized 5% platinum on activated charcoal as catalyst.

Sources & evidence

ORD record
ord-e8d522632f964c7f9fd738debfffeb3e
Source dataset
uspto-grants-1991_03
Patent number
US04999352

Reaction notes

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