Formic Acid → HCID 20063610, compound

HRID 359641Notes

Reaction equation

HRID 359641 reaction equation
[NH2:1][C:2]1[C:7]([O:8][CH3:9])=[C:6]([N+:10]([O-:12])=[O:11])[C:5]([O:13][CH3:14])=[CH:4][C:3]=1[O:15][CH3:16].[CH:17](O)=[O:18]>O>[CH:17]([NH:1][C:2]1[C:7]([O:8][CH3:9])=[C:6]([N+:10]([O-:12])=[O:11])[C:5]([O:13][CH3:14])=[CH:4][C:3]=1[O:15][CH3:16])=[O:18]

Participants

4

Reactant 2

HCID 284Formic AcidHCID 23009735HCID 23009735, compound

Product 1

HCID 20063610HCID 20063610, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A mixture comprising 0.11 mole (26.6 g) of 2-amino-4-nitro-1,3,5-trimethoxybenzene and 55 ml of formic acid are refluxed during three hours. The reaction mixture is cooled and diluted with iced water. The expected product precipitates and is separated by filtration. After drying it is recrystallized from ethanol. It melts at 98° C.

Workup

  1. temperatureThe reaction mixture is cooled
  2. customThe expected product precipitates
  3. customis separated by filtration
  4. customAfter drying it
  5. customis recrystallized from ethanol

Sources & evidence

ORD record
ord-29fa187fbf714e038a1767d6e11d47d9
Source dataset
uspto-grants-1991_03
Patent number
US05002585

Reaction notes

Loading…