1,2-Diallyloxybenzene → 1,2-Diallyloxybenzene

HRID 361158Notes

Reaction equation

HRID 361158 reaction equation
C=CCOc1ccccc1OCC=C>CCOC(C)=O.O=C1CC[C@H]2CO[C@@H]1O2>C=CCc1ccc(CC=C)c(O)c1O.C=CCc1ccc(O)c(O)c1CC=C

Participants

7

Reactant 1

HCID 778941,2-Diallyloxybenzene

Product 3

HCID 778941,2-DiallyloxybenzeneYield 65.319%HCID 131583253,4-Diallylbenzene-1,2-diolYield 4.358%HCID 132276783,6-Bis(prop-2-enyl)benzene-1,2-diolYield 4.565%

Reagents, catalysts & solvents 3

HCID 8857Ethyl AcetateSolventHCID 10975499(1S,5R)-6,8-Dioxabicyclo[3.2.1]octan-4-oneSolventHCID 7500EthylbenzeneInternal standard

Conditions

Temperature
200 °C
Other
Reaction carried out in transient flow with ramps to vary the binary solvent composition, temperature and residence time. This reaction represents a single HPLC measurement sampled from within a transient flow ramp. Conditions are an estimate of what the reaction sample was exposed to prior to analysis.

Workup

  1. temperatureThe solution flowed through a customized cooling system made from an aluminum block and a Peltier assembly to quench the reaction.
  2. aliquotA Vici 4 port 2 position sampling valve sampled small aliquots (500 nL) into the HPLC for online analysis measurements of the reaction.

Sources & evidence

ORD record
ord-a018ee3ce5394bc68f488872fd1638d8
Source dataset
Transient flow exploration of the effect of temperature, residence time and binary solvent ratios on a uni-molecular allyl substituted catechol reaction.
Original link
View source

Reaction notes

Loading…