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HRID361862

反应详情

EQUATION

反应方程式

HRID 361862 的结构方程式

REACTANTS

反应物

1
结构：COC(=O)C(=Cc1ccc(OCc2ccccc2)cc1)N=[N+]=[N-]
HCID54271879

未命名化合物

PRODUCTS

生成物

1
结构：COC(=O)c1cc2ccc(OCc3ccccc3)cc2[nH]1
HCID4715068

methyl 6-(benzyloxy)-1H-indole-2-carboxylate

C17H15NO3

AUXILIARIES

试剂、催化剂与溶剂

1
结构：Cc1ccccc1
溶剂HCID1140

Toluene

C7H8

PROCEDURE

实验过程

Methyl 4-benzyloxy-α-azidocinnamate (EXAMPLE 246, 5.8 g) is dissolved in 376 ml of toluene and the reaction is heated to reflux for 1 hr. Then the reaction is cooled, concentrated under reduced pressure and the solids are recrystallized from ethyl acetate/hexane to provide the title compound.

WORKUP

后处理

  1. temperaturethe reaction is heated
  2. temperatureto reflux for 1 hr
  3. temperatureThen the reaction is cooled
  4. concentrationconcentrated under reduced pressure
  5. customthe solids are recrystallized from ethyl acetate/hexane