HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 67598507, compound → HCID 67598837, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 67598507 | HCID 67598507 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Solvent | Hexane | HCID 8058 | — |
| Product | HCID 67598837 | HCID 67598837 | 83.5% |
Reaction Steps
To a suspension of Cp2ZrHCl (2.58 g) in dry THF (50 mL) was added 2-fluoro-3-(tributylstannylethynyl)pyridine (2.05 g). After 2 hours the mixture was diluted with hexane and filtered through a short silica gel column. Evaporation of the solvents gave Z-2-fluoro-3-(2-tributylstannylethenyl)pyridine as an oil (1.72 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05869482 |
| Source dataset | uspto-grants-1999_02 |
| ORD ID | ord-6757c9f895f747f8992d675ec6608380 |
| Source note | uspto-grants-1999_02 |