Sulfuryl chloride → HCID 15346385, compound

HRID 362648Notes

Reaction equation

HRID 362648 reaction equation
[NH2:1][C:2]1[N:6]([C:7]2[CH:11]=[C:10]([O:12][CH:13]([F:15])[F:14])[N:9]([CH3:16])[N:8]=2)[N:5]=[CH:4][C:3]=1[C:17]#[N:18].S(Cl)([Cl:22])(=O)=O>C(#N)C>[NH2:1][C:2]1[N:6]([C:7]2[C:11]([Cl:22])=[C:10]([O:12][CH:13]([F:14])[F:15])[N:9]([CH3:16])[N:8]=2)[N:5]=[CH:4][C:3]=1[C:17]#[N:18]

Participants

4

Reactant 2

HCID 24648Sulfuryl chlorideHCID 53746681HCID 53746681, compound

Product 1

HCID 15346385HCID 15346385, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

5.0 g (19.7 mmol) 5-Amino-1-(5-difluoromethoxy-1-methyl-3-pyrazolyl)-4-pyrazolecarbonitrile was dissolved in 180 ml acetonitrile and 2.65 g (19.7 mmol) sulfuryl chloride added dropwise. The mixture was stirred for one hour at room temperature and concentrated.

Workup

  1. concentrationconcentrated

Sources & evidence

ORD record
ord-ab1aa04b68bc471cb27c3c641dc7393a
Source dataset
uspto-grants-1999_02
Patent number
US05869686

Reaction notes

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