2-(2-Ethylhexyloxy)ethanol → HCID 4089548, compound

HRID 363202Notes

Reaction equation

HRID 363202 reaction equation
[CH2:1]([CH:3]([CH2:9][CH2:10][CH2:11][CH3:12])[CH2:4][O:5][CH2:6][CH2:7]O)[CH3:2].S(Cl)([Cl:15])=O>>[CH2:1]([CH:3]([CH2:9][CH2:10][CH2:11][CH3:12])[CH2:4][O:5][CH2:6][CH2:7][Cl:15])[CH3:2]

Participants

3

Reactant 2

HCID 152602-(2-Ethylhexyloxy)ethanolHCID 24386Thionyl Chloride

Product 1

HCID 4089548HCID 4089548, compoundYield 94.2%

Procedure

500 g (2.81 mol) of 2-(2-ethylhexyloxy)ethanol and 500 g of thionyl chloride were placed in a 2-liter four-neck flask and refluxed with heat for 2 hours. Subsequently, a distillation under reduced pressure was conducted to obtain 510 g of 2-(2-ethylhexyloxy)ethylchloride as a colorless oil.

Workup

  1. temperaturerefluxed
  2. temperaturewith heat for 2 hours
  3. distillationSubsequently, a distillation under reduced pressure

Sources & evidence

ORD record
ord-36df7e95c51846788f77bd32bd1c86af
Source dataset
uspto-grants-1999_02
Patent number
US05872272

Reaction notes

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