Allylamine → HCID 178440549, compound

HRID 364151Notes

Reaction equation

HRID 364151 reaction equation
[CH2:1]([CH2:4][C:5]12[CH2:11][CH:8]([CH:9]=[CH:10]1)[CH:7]1[C:12]([O:14][C:15](=[O:16])[CH:6]21)=[O:13])[CH:2]=[CH2:3].[CH2:17]([NH2:20])[CH:18]=[CH2:19]>>[CH2:17]([N:20]=[C:15]([CH:6]1[CH:7]([C:12]([OH:14])=[O:13])[CH:8]2[CH2:11][C:5]1([CH2:4][CH2:1][CH:2]=[CH2:3])[CH:10]=[CH:9]2)[OH:16])[CH:18]=[CH2:19]

Participants

3

Reactant 2

HCID 7853AllylamineHCID 53956536HCID 53956536, compound

Product 1

HCID 178440549HCID 178440549, compound

Procedure

A mixture of 30 g of allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride and 9.41 g of allylamine is heated at reflux temperature for 2 hours, water is removed by distillation, and the product is rectified at 119°-127° C. and 2.66 Pa. This gives 30.24 g (85.5% of theory) of a pale yellow oil having the following characteristic data: nD20 =1.5202, η25 =0.135 Pa.s.

Workup

  1. temperatureis heated
  2. temperatureat reflux temperature for 2 hours
  3. customwater is removed by distillation
  4. customis rectified at 119°-127° C.

Sources & evidence

ORD record
ord-042534f800414a3ca2b958a6295f4bf0
Source dataset
uspto-grants-1986_08
Patent number
US04604437

Reaction notes

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