1,2-Dichloroethane → HCID 20239857, compound

HRID 364769Notes

Reaction equation

[CH3:1][C:2]1[CH:3]=[C:4]([OH:9])[CH:5]=[CH:6][C:7]=1[CH3:8].[CH:10]1[C:15](O)=[CH:14][CH:13]=[CH:12][C:11]=1[CH3:17].[CH2:18](Cl)CCl>>[OH:9][C:4]1[C:5]2[C:14]([CH3:15])([CH3:18])[CH2:13][CH2:12][C:11]([CH3:10])([CH3:17])[C:6]=2[C:7]([CH3:8])=[C:2]([CH3:1])[CH:3]=1

Participants

Reactant 3

HCID 111,2-Dichloroethane

HCID 342M-Cresol

HCID 72493,4-Dimethylphenol

Product 1

HCID 20239857HCID 20239857, compound

Procedure

Employing procedures and materials similar to those described in Example 1, except that 3,4-dimethylphenol was substituted for m-cresol, and the reaction was carried out in the presence of ethylene dichloride as solvent, there was obtained 1-hydroxy-3,4,5,5,8,8-hexamethyl-5,6,7,8-tetrahydronaphthalene, 15% theor., GLC purity 100%, exhibiting the expected spectral data.

Sources & evidence

ORD record: ord-e4afeb7420334db488c9275f37ccf438
Source dataset: uspto-grants-1986_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04605778

Reaction notes

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