Boron trifluoride etherate → HCID 70253210, compound

HRID 366376Notes

Reaction equation

HRID 366376 reaction equation
[NH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8]#[N:9].[CH2:10]1[CH2:20][C:18](=O)[C:17]2[C:12](=[CH:13][CH:14]=[CH:15][CH:16]=2)[CH2:11]1.B(F)(F)F.CCOCC>>[NH2:1][C:2]1[C:3]2[C:8]3[N:9]=[C:17]4[C:12]([CH:11]=[CH:10][CH:20]=[CH:18]4)=[CH:13][C:14]=3[CH2:15][CH2:16][C:4]=2[CH:5]=[CH:6][CH:7]=1

Participants

4

Reactant 3

HCID 8000Boron trifluoride etherateHCID 107241-TetraloneHCID 729132-Aminobenzonitrile

Product 1

HCID 70253210HCID 70253210, compound

Procedure

2-amino-1-cyano-benzene (2.0 g, 16.9 mmol), α-tetralone (3, 4-dihydro-[2H]-naphthalene-1-one) (Aldrich Chemicals) (2.7 g, 18.5 mmol) and boron trifluoride diethyl etherate (1M, 2.3 ml, 18.8 mmol) were treated according to the general procedure described herein to give the title compound.

Sources & evidence

ORD record
ord-94427e630a1a4856b8c092b4eb738b16
Source dataset
uspto-grants-2000_10
Patent number
US06130228

Reaction notes

Loading…